4-Hydroxy--butanone
:
纯度:98%
CAS:
英文名称:4-Hydroxy--butanone
4-Hydroxy--butanone 用于制备稠合苯并氮杂分子作为具有药学活性的选择性 D 受体拮抗剂。也用于制备verrucarin和甲羟戊酸内酯。此外,它还用于在锐钛矿二氧化钛催化剂上通过脱水制备-丁烯--酮。它还用于制备 4-甲基-5-羟甲基噻唑、(±)-lineatin 和 β-羟基内酯。
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[]. Gisèle El Dib, et al. First experimental determination of the absolute gas-phase rate coefficient for the reaction of OH with 4-hydroxy--butanone (4HB) at 94 K by vapor pressure measurements of 4HB. J Phys Chem A. 0 Jan 0;7():7-5.
[]. Hon Wai Lam, et al. Cu(I)-catalyzed reductive aldol cyclizations: diastereo- and enantioselective synthesis of beta-hydroxylactones. Org Lett. 005 Sep 5;7(9):45-8.
[]. Liang Wang, et al. Nanotube-supported bioproduction of 4-hydroxy--butanone via in situ cofactor regeneration. Appl Microbiol Biotechnol. 0 Jun;94(5):-4.
P0-P-P40-P4-P4-P4-P80-P70+P78-P50
的合成线路
-
~95%
参考文献:
Hitchcock Perron Martin Albizati Synthesis, 990 , # p. 059 - 06
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~7%
参考文献:
Kobayashi, Kazuhiro Akamatsu, Hideki Takada, Keiichiro Morikawa, Osamu Konishi, Hisatoshi Tetrahedron Letters, 996 , vol. 7, # 4 p. 47 - 440
-
~0%
参考文献:
Yoshida, Jun-ichi Nakai, Ryoichi Kawabata, Nariyoshi Journal of Organic Chemistry, 980 , vol. 45, # 6 p. 569 - 57
-
~9%
参考文献:
Li, Jun Menche, Dirk Synthesis, 009 , # art. no. Z0709SS, p. 904 - 908
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~94%
参考文献:
Li, Jun Menche, Dirk Synthesis, 009 , # art. no. Z0709SS, p. 904 - 908
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